WebJan 8, 2008 · In the racemization of aliphatic amines over Raney catalysts, the selectivity is very high, with the enantiomeric amine as the sole product. DKR of racemic aliphatic … WebTY - THES. T1 - Development of racemization catalysts for dynamic kinetic resolution. AU - Mavrynsky, Denys. PY - 2012. Y1 - 2012. KW - 116 Chemical sciences

Highly active enzyme–metal nanohybrids synthesized in ... - Nature

WebThe article was published on 2013-07-31. It has received 10 citation(s) till now. The article focuses on the topic(s): Racemization & Kinetic resolution. WebAn account of the development of Lewis-acid-catalyzed methods for racemization-free peptide synthesis is presented. These methods are based on the substrate control concept that has been exploited extensively in stereoselective reactions, but the concept has never previously been applied to peptide synthesis. The most important difference that has … dra04775

IJMS Free Full-Text Racemization of the Succinimide …

In chemistry, racemization is a conversion, by heat or by chemical reaction, of an optically active compound into a racemic (optically inactive) form. This creates a 1:1 molar ratio of enantiomers and is referred to as a racemic mixture (i.e. contain equal amount of (+) and (−) forms). Plus and minus forms are called Dextrorotation and levorotation. The D and L enantiomers are present in equal quantities, the resulting sample is described as a racemic mixture or a racemate. Racemiza… Webthe racemization reaction occurs only under harsh conditions, such as irradiation by strong light, prolonged heating at very high temperatures, or addition of metal catalyst, chiral … WebAmicoTA catalyzed transamination at 30–60 °C and pH 6–10 ... Moreover, it remains unclear how DAATs escape the side reaction of racemization. The mechanism of the … radio d plus frekvencija podgorica